云南省富乐铅锌矿床闪锌矿中微量元素地球化学特征——兼论深色闪锌矿富集Cd的原因   总被引：3，自引：0，他引：3  

司荣军  顾雪祥  肖淳  于海涛  王中伟  陈彦交  邱宁 《矿物岩石》2011,31(3)

富乐铅锌矿床位于川滇黔铅锌多金属成矿域东南部,其闪锌矿中Cd含量居全国前列。单矿物常量分析表明闪锌矿内w(Fe)低,平均0.23%。微量分析和电子探针微区分析显示,微量元素w(B)主要为Cd 16 183×10-6,Cu 1 514×10-6;Ni 414×10-6;As215×10-6;Se 163×10-6;Ge 135×10-6;Ga 86×10-6;Sb 35×10-6;Ag 16×10-6,其次为Cr,Co,Mn,Ba,Ti,Sr,Mo等,其含量一般1×10-6～10×10-6。Cd与Cu,Ag,Sb,As,Ni等呈正相关。闪锌矿的颜色由这些微量元素共同引起,Ni使闪锌矿呈紫色,Cu使闪锌矿呈红色,Ga使闪锌矿呈黄色。Cd不影响闪锌矿颜色,Cd之所以在深色闪锌矿中相对富集,是因为Cd与引起闪锌矿颜色改变的这些微量元素含量正相关,它们同步进入闪锌矿的晶格。Fe因为含量过低,对闪锌矿颜色影响不明显。  相似文献   

贵州纳雍水东铅锌矿矿床地球化学特征   总被引：2，自引：0，他引：2  

吴波  陈国勇  陶平  谯文浪 《贵州地质》2011,28(2):108-113

对贵州纳雍水东乡洗米沟、坟山脚一带灯影组地层中铅锌矿石采样,进行镜下观察和全岩主量、微量元素、稀土元素以及硫同位素地球化学研究。微量元素研究表明,矿床中N i、Mo、As、Sb等成矿元素富集明显,Sr、Ba、V等元素强烈亏损,认为早寒武世热水对铅锌矿源层进行了淋滤和改造;稀土元素研究表明,铅锌矿石稀土配分曲线向右倾斜,...  相似文献   

泥岩渗流-应力耦合蠕变损伤模型研究(Ⅱ):数值仿真和参数反演     

贾善坡  陈卫忠  于洪丹  李香玲 《岩土力学》2011,32(10):3163-3170

进一步分析了第Ⅰ部分[1]提出的泥岩渗流-应力耦合蠕变损伤模型。在连续损伤力学理论和比奥(Biot)理论的基础上,导出了考虑渗流-应力-损伤耦合的蠕变损伤有限元格式,建立了弹性预测、塑性修正、损伤修正-渗透系数修正的数值分析框架,编制了非线性有限元分析程序。根据监测的衬砌长期变形数据,采用优化反分析法获得了蠕变损伤模型中的待定参数,并应用于比利时核废料库施工过程中泥岩巷道围岩渗流-应力耦合过程、损伤演化以及长期稳定性分析,研究结果表明,泥岩开挖后渗透性明显增大,约为原岩的120倍,蠕变效应导致泥岩裂隙和渗透性自愈合,约3.5年后渗透性基本恢复到原岩的数量级,围岩中部的蠕变明显大于顶部和底部。研究成果对软岩隧洞长期稳定性的预测与预报具有一定的参考意义。  相似文献   

澳大利亚布朗斯(Browns)Co-Cu-Ni多金属矿床地球化学特征及与中国南方黑色岩系金属矿床对比     

王明艳  王安建  邓圣富  刘伟  张德贤 《大地构造与成矿学》2011,35(1):105-117

黑色岩系中金属元素地球化学特征一直是矿床地质研究的重点.澳大利亚布朗斯Co-Cu-Ni多金属矿产于古元古代黑色岩系中,属典型的层控矿床;该矿床中主要成矿元素为Co、Cu、Ni和Pb,矿化分带不明显,蚀变微弱.δ34S均值范围为-5.21‰～14.78‰,估计生物成因的硫占一定比例,后期有细菌还原硫酸盐成因的高硫同位素组...  相似文献   

中国南方地区水系沉积物中元素丰度   总被引：6，自引：0，他引：6       下载免费PDF全文

程志中  谢学锦  潘含江  杨榕  商云涛 《地学前缘》2011,18(5):289-295

从中国南方12个省自治区230万km2面积上所采集的水系沉积物中按每1∶5万图幅一个组合样的密度组合成5 244件组合样,采用以ICP-MS、ICP-AES和XRF为主的先进的分析测试方法和严格的质量控制方法,准确测试了其中的76种元素。统计计算了中国南方地区76种元素的平均值,给出了中国南方地区水系沉积物中76种元素...  相似文献   

日照茶树种植区表层土壤营养元素地球化学特征分析     

王学  张祖陆  王茂香  张伦  代杰瑞 《山东地质》2011,(6):18-22

对土壤中的营养元素进行分析,对于茶树种植及宜种性评价意义深远。该研究主要是利用1 km×1 km表层土壤采样数据,借助地统计学和GIS技术对日照茶树种植区表层土壤中主要营养元素的地球化学特征进行分析。结果表明,研究区N,P,K2O,S含量相对较丰富,而其他营养元素相对较贫乏;营养元素富集区大致以西湖、秦楼、岚山头3个镇为顶点呈三角分布。  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111000405   总被引：1，自引：0，他引：1  

Jean de la Paix Mupenzi  Lanhai Li  Jiwen Ge  Achal Varenyam  Gabriel Habiyaremye  Nzayisenga Theoneste  Kamanzi Emmanuel 《地学前缘(英文版)》2011,2(4):599-607

This study has focused on the processes of soil degradation and chemical element concentration in tea-growing regions of Rwanda, Africa. Soil degradation accelerated by erosion is caused not only by topography but also by human activities. This soil degradation involves both the physical loss and reduction in the amount of topsoil associated with nutrient decline. Soil samples were collected from eleven tropical zones in Rwanda and from variable depth within each collecting site. Of these, Samples from three locations in each zone were analyzed in the laboratory, with the result that the pH of all soil samples is shown to be less than 5 (pH < 5) with a general average of 4.4. The elements such as iron (Fe), copper (Cu), manganese (Mn), and zinc (Zn) are present in high concentration levels. In contrast calcium (Ca) and sodium (Na) are present at low-level concentrations and carbon (C) was found in minimal concentrations. In addition, elements derived from fertilizers, such as nitrogen (N), phosphorous (P), and potassium (K) which is also from minerals such as feldspar, are also present in low-level concentrations. The results indicate that the soil in certain Rwandan tea plantations is acidic and that this level of pH may help explain, in addition to natural factors, the deficiency of some elements such as Ca, Mg, P and N. The use of chemical fertilizers, land use system and the location of fields relative to household plots are also considered to help explain why tea plantation soils are typically degraded.  相似文献   

长江口水下三角洲沉积物记录的古环境演化   总被引：4，自引：0，他引：4  

张瑞虎  谢建磊  刘韬  赵宝成 《海洋地质与第四纪地质》2011,(1):1-10

长江口水下三角洲60 m的HYZK5钻孔,揭示了末次冰期以来河流相、滨海湖沼相、河口湾-浅海相(前三角洲相)和水下汉道相的沉积环境演化.泥炭层形成于末次冰期的冷湿气候环境;有孔虫丰度的变化反映了12 000 cal.aBP以来海平面迅速上升,但在11 200～10 000 cal.aBP出现短暂的停顿.沉积物的粒度、磁...  相似文献   

海南岛三亚小东海岸礁礁坪沉积物的稀土元素分布特征   总被引：1，自引：0，他引：1  

王月  沈建伟  王旭  杨红强  刘苗苗 《海洋地质与第四纪地质》2011,(5):59-66

对海南岛三亚小东海东北岸礁礁坪表面沉积物的稀土元素进行了分析,结果表明,沉积物的∑REE为80.22mg/kg,稀土元素含量球粒陨石标准化分布模式呈现轻稀土富集、重稀土亏损,Eu明显负异常(0.58),Ce无异常,Y/Ho低(27.60)的陆相模式特征.根据小东海礁坪沉积样品稀土元素的空间分布情况可以推测出礁坪珊瑚表面...  相似文献   

Rare earth elements in suspended and bottom sediments of the Mandovi estuary, central west coast of India: Influence of mining     

R. ShynuV. Purnachandra Rao  Pratima M. KessarkarT.G. Rao 《Estuarine, Coastal and Shelf Science》2011,94(4):355-368

Rare earth elements (REEs) in the suspended particulate matter (SPM) of the Mandovi estuary indicated that the mean total-REEs (∑REE) and light REE to heavy REE ratios are lower than that of the average suspended sediment in World Rivers and Post-Archean average Australian shale. High ∑REE were associated with high SPM/low salinity and also with high SPM/high salinity. Although the ∑REE broadly agree with SPM levels at each station, their seasonal distributions along transect are different. SPM increased seaward in the estuary both during the monsoon and pre-monsoon, but consistently low at all stations during the post-monsoon. The mean ∑REE decreased marginally seaward and was <25% at sea-end station than at river-end station. Spatial variations in ∑REE are maximum (64%) during the pre-monsoon. Strong to moderate correlation of ∑REE with Al, Fe and Mn in all seasons indicates adsorption and co-precipitation of REEs with aluminosilicate phases and Fe, Mn-oxyhydroxides. The ratio of mean ∑REE in sediment/SPM is low during the monsoon (1.27), followed by pre-monsoon (1.5) and post-monsoon (1.62). The middle REE- and heavy REE-enriched patterns with positive Ce and Eu anomalies are characteristic at every station and season, both in SPM and sediment. They also exhibit tetrad effect with distinct third and fourth tetrads. Fe-Mn ore dust is the most dominant source for REEs. However, the seasonal changes in the supply of detrital silicates, Fe-Mn ore dust and particulates resuspended from bottom sediments diluted the overall effect of salinity on fractionation and distribution of REEs in the estuary.  相似文献